A safer, greener way to make solar cells: Researchers find replacement for toxic solvent

MAY 19, 2021, by Swansea University

https://techxplore.com/news/2021-05-safer-greener-solar-cells-toxic.html

Carys Worsley at work in the SPECIFIC laboratories at Swansea University, where she has led research to develop a greener solvent for use in the next generation of solar technology—printed carbon perovskite cells.

 Credit: SPECIFIC, Swansea University

Scientists at SPECIFIC Innovation and Knowledge Centre, Swansea University, have found a way to replace the toxic, unsustainable solvents currently needed to make the next generation of solar technology.

Printed carbon perovskite solar cells have been described as a likely front runner to the market because they are extremely efficient at converting light to electricity, cheap and easy to make.

A major barrier to the large-scale manufacture and commercialization of these cells is the solvents used to control crystallization of the perovskite during fabrication: This is because they are made from unsustainable materials and are banned in many countries due to their toxicity and psychoactive effects.

SPECIFIC's researchers have discovered that a non-toxic biodegradable solvent called γ-Valerolactone (GVL) could replace these solvents without impacting cell performance.

GVL's list of advantages could improve the commercial viability of carbon perovskite solar devices:
It is made from sustainable feedstocks
There are no legal issues in its use around the world
It is suitable for use in large-scale manufacturing processes
It is non-toxic and biodegradable

Carys Worsley, who led the research as part of her doctorate, said:

Left - solvent normally used to make solar cells, which is toxic. 

Right - new green solvent developed by Swansea University researchers from the SPECIFIC project.

 Credit: SPECIFIC, Swansea University

"To be truly environmentally sustainable, the way that solar cells are made must be as green as the energy they produce. As the next generation of solar technologies approaches commercial viability, research to reduce the environmental impact of large-scale production will become increasingly important."

Professor Trystan Watson, research group leader, added:

"Many problems need to be resolved before these technologies become a commercial reality. This solvent problem was a major barrier, not only restricting large-scale manufacture but holding back research in countries where the solvents are banned.

We hope our discovery will enable countries that have previously been unable to participate in this research to become part of the community and accelerate the development of cleaner, greener energy."

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